Notes
Slide Show
Outline
1
"Ping Hou"
  • Ping Hou
  • Nortel Networks Co.
  • Richard Sun
  • Angstrom Sun Technologies Inc.
2
Introduction
  •           Titanium oxide (TiO2) thin film has been widely used as optical coatings due to its high index of refraction. It is well known that structures and properties of TiO2 films are highly dependent on the processing techniques. E-beam evaporation has long been recognized as a practical way of depositing optical thin films. However, preparing a homogenous TiO2 film with this technique is still a challenge. One of the difficulties of getting a structurally uniform TiO2 film lies in the fact of its low phase transformation temperature. It is vital to find a fast and non-destructive way to monitor and evaluate the film optical quality. It is also important to tail the film stress at will to satisfy mechanical requirements for MEMs devices, such as vertical cavity surface emission laser (VCSEL). To this end, the stress and structural homogeneity of e-beam evaporated TiO2 films will be examined and discussed in this research.
3
Deposition Chamber
4
Deposition Process
5
Model and Its Analyses
6
Analysis Model
7
Spectra Fittings¾Three Sub-Layer Model
8
Graded Optical Constants of TiO2 Film
9
Microscope Observation
10
Chamber Temperature Variance
11
Co-deposited TiO2-SiO2 Film
12
Surface Micrographs
13
TiO2 Film Stress Dependency
14
Summary
  • TiO2 film stress can be tuned through properly adjusting the deposition parameters, especially anode current of the ion gun.
  • Spectroscopic ellipsometry has been successfully used as a nondestructive technique to characterize the structural discrepancy of TiO2 films.
  • Three sub-layer model can be used to describe the heterogeneity of as-deposited TiO2 films, which is caused mainly by the chamber temperature changes during the deposition.
  • With TiO2-SiO2 co-deposition, a homogeneous film can be produced. At the same time, refractive index can be further tuned through controlling the ratio of TiO2 to SiO2 fraction in the film.